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Enhancement of the Rate of Pyrophosphate Hydrolysis by Nonenzymatic Catalysts and by Inorganic Pyrophosphatase
To estimate the proficiency of inorganic pyrophosphatase as a catalyst, (31)P NMR was used to determine rate constants and thermodynamics of activation for the spontaneous hydrolysis of inorganic pyrophosphate (PP(i)) in the presence and absence of Mg(2+) at elevated temperatures. These values were...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Society for Biochemistry and Molecular Biology
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3099670/ https://ncbi.nlm.nih.gov/pubmed/21460215 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M110.214510 |
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