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The hydrolysis of phosphate diesters in cyclohexane and acetone
The hydrolysis of phosphate diesters is one of the most difficult reactions known. Here we show that in acetone or cyclohexane, at 25 °C, phosphodiesters undergo hydrolysis 5 × 10(5) and 2 × 10(9)-fold more rapidly than in water, respectively, and that this rate enhancement is achieved by lowering t...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2904243/ https://ncbi.nlm.nih.gov/pubmed/20448876 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c0cc00229a |
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