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Insights into the different dioxygen activation pathways of methane and toluene monooxygenase hydroxylases

The methane and toluene monooxygenase hydroxylases (MMOH and TMOH, respectively) have almost identical active sites yet the physical and chemical properties of their oxygenated intermediates, designated P(*), H(peroxo), Q and Q(*) in MMOH and ToMOH(peroxo) in ToMOH, are substantially different. We r...

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Bibliografiset tiedot
Päätekijät: Bochevarov, Arteum D., Li, Jianing, Song, Woon Ju, Friesner, Richard A., Lippard, Stephen J.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2011
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC3092846/
https://ncbi.nlm.nih.gov/pubmed/21517016
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja110287y
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