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Insights into the different dioxygen activation pathways of methane and toluene monooxygenase hydroxylases
The methane and toluene monooxygenase hydroxylases (MMOH and TMOH, respectively) have almost identical active sites yet the physical and chemical properties of their oxygenated intermediates, designated P(*), H(peroxo), Q and Q(*) in MMOH and ToMOH(peroxo) in ToMOH, are substantially different. We r...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3092846/ https://ncbi.nlm.nih.gov/pubmed/21517016 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja110287y |
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