Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts

Atom transfer radical addition of haloalkanes and α-halocarbonyls to olefins is efficiently performed with the photocatalyst Ir[(dF(CF(3))ppy)(2)(dtbbpy)]PF(6). This protocol is characterized by excellent yields, mild conditions, low catalyst loading, and broad scope. In addition, the atom transfer...

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Bibliographic Details
Main Authors: Nguyen, John D., Tucker, Joseph W., Konieczynska, Marlena D., Stephenson, Corey R. J.
Format: Artigo
Language:Inglês
Published: 2011
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3086499/
https://ncbi.nlm.nih.gov/pubmed/21381734
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja108560e
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