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Ni(0)-Catalyzed 1,4-Selective Diboration of Conjugated Dienes

[Image: see text] A catalytic stereoselective 1,4-diboration of conjugated dienes with B(2)(pin)(2) was accomplished with Ni(cod)(2) and PCy(3) as the catalyst. This reaction broadens the substrate scope of current methods for catalytic diene diboration by including internal and sterically hindered...

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Main Authors: Ely, Robert J., Morken, James P.
格式: Artigo
語言:Inglês
出版: 2010
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3086412/
https://ncbi.nlm.nih.gov/pubmed/20828186
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101797f
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