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Kinetic challenges facing oxalate, malonate, acetoacetate and oxaloacetate decarboxylases

To compare the power of the corresponding enzymes as catalysts, the rates of uncatalyzed decarboxylation of several aliphatic acids (oxalate, malonate, acetoacetate and oxaloacetate) were determined at elevated temperatures and extrapolated to 25 °C. In the extreme case of oxalate, the rate of the u...

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Autors principals: Wolfenden, Richard, Lewis, Charles A., Yuan, Yang
Format: Artigo
Idioma:Inglês
Publicat: 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3077560/
https://ncbi.nlm.nih.gov/pubmed/21434608
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja111457h
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