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Kinetic challenges facing oxalate, malonate, acetoacetate and oxaloacetate decarboxylases

To compare the power of the corresponding enzymes as catalysts, the rates of uncatalyzed decarboxylation of several aliphatic acids (oxalate, malonate, acetoacetate and oxaloacetate) were determined at elevated temperatures and extrapolated to 25 °C. In the extreme case of oxalate, the rate of the u...

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Detalhes bibliográficos
Main Authors: Wolfenden, Richard, Lewis, Charles A., Yuan, Yang
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3077560/
https://ncbi.nlm.nih.gov/pubmed/21434608
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja111457h
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