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Why Do Some Fischer Indolizations Fail?
The mechanisms of the Fischer indole synthesis and competing cleavage pathways were explored with SCS-MP2/6-31G(d) and aqueous solvation calculations. Electron-donating substituents divert the reaction pathway to heterolytic N–N bond cleavage and preclude the acid-promoted [3,3]-sigmatropic rearrang...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2011
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3076556/ https://ncbi.nlm.nih.gov/pubmed/21443189 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201035b |
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