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Synthesis of the Cytotrienin A Core via Metal Catalyzed C-C Coupling
[Image: see text] A synthetic approach to the C17-benzene ansamycins via metal catalyzed C-C coupling is described. Key bond formations include direct iridium catalyzed carbonyl crotylation from the alcohol oxidation level followed by chelation-controlled Sakurai-Seyferth dienylation to form the ste...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3075014/ https://ncbi.nlm.nih.gov/pubmed/21323372 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol200160p |
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