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C–O Hydrogenolysis Catalyzed by Pd-PMHS Nanoparticles in the Company of Chloroarenes
[Image: see text] Catalytic Pd(OAc)(2) and polymethylhydrosiloxane (PMHS), in conjunction with aqueous KF, and a catalytic amount of an aromatic chloride, effects the chemo, regio, and stereoselective deoxygenation of benzylic oxygenated substrates at room temperature in THF. Preliminary mechanistic...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3073151/ https://ncbi.nlm.nih.gov/pubmed/21247081 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol102757v |
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