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Detection of formate, rather than carbon monoxide, as the stoichiometric co-product in conversion of fatty aldehydes to alkanes by a cyanobacterial aldehyde decarbonylase
The second of two reactions in a recently discovered pathway through which saturated fatty acids are converted to alkanes (and unsaturated fatty acids to alkenes) in cyanobacteria entails scission of the C1–C2 bond of a fatty aldehyde intermediate by the enzyme aldehyde decarbonylase (AD), a ferriti...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2011
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3069495/ https://ncbi.nlm.nih.gov/pubmed/21341652 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja111607x |
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