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Asymmetric Ni-Catalyzed Conjugate Allylation of Activated Enones

[Image: see text] The nickel-catalyzed enantioselective addition of allylboronic acid pinacol ester - allylB(pin) – is described. This reaction is highly effective with dialkylidene ketones and favors the allylation of the benzylidene site in non-symmetric substrates. The reaction appears to proceed...

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Hlavní autoři: Sieber, Joshua D., Morken, James P.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2008
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3065355/
https://ncbi.nlm.nih.gov/pubmed/18338891
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja710922h
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