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Photocycloaddition of aromatic and aliphatic aldehydes to isoxazoles: Cycloaddition reactivity and stability studies

The first photocycloadditions of aromatic and aliphatic aldehydes to methylated isoxazoles are reported. The reactions lead solely to the exo-adducts with high regio- and diastereoselectivities. Ring methylation of the isoxazole substrates is crucial for high conversions and product stability. The 6...

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Main Authors: Griesbeck, Axel G, Franke, Marco, Neudörfl, Jörg, Kotaka, Hidehiro
Formato: Artigo
Idioma:Inglês
Publicado: Beilstein-Institut 2011
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3063004/
https://ncbi.nlm.nih.gov/pubmed/21448241
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.18
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