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Overturning Indolyne Regioselectivities and Synthesis of Indolactam V
We report the design and synthesis of an indolyne that displays a reversal in regioselectivity, in both nucleophilic addition and cycloaddition reactions, compared to typical 4,5-indolynes. Our approach utilizes simple computations to predict regioselectivity in reactions of unsymmetrical arynes. Wi...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3060274/ https://ncbi.nlm.nih.gov/pubmed/21351773 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja200437g |
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