Direct demonstration of the isomerization component of the monoterpene cyclase reaction using a cyclopropylcarbinyl pyrophosphate substrate analog.

The tightly coupled nature of the reaction sequence catalyzed by monoterpene cyclases has precluded direct observation of the topologically required isomerization step leading from geranyl pyrophosphate to the presumptive, enzyme-bound, tertiary allylic intermediate linalyl pyrophosphate, which ulti...

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Vydáno v:	Proc Natl Acad Sci U S A
Hlavní autoři:	Wheeler, C J, Croteau, R B
Médium:	Artigo
Jazyk:	Inglês
Vydáno:	National Academy of Sciences 1987
Témata:	Research Article
On-line přístup:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC305204/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3474630/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.84.14.4856
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