Direct demonstration of the isomerization component of the monoterpene cyclase reaction using a cyclopropylcarbinyl pyrophosphate substrate analog.

The tightly coupled nature of the reaction sequence catalyzed by monoterpene cyclases has precluded direct observation of the topologically required isomerization step leading from geranyl pyrophosphate to the presumptive, enzyme-bound, tertiary allylic intermediate linalyl pyrophosphate, which ulti...

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Опубліковано в::	Proc Natl Acad Sci U S A
Автори:	Wheeler, C J, Croteau, R B
Формат:	Artigo
Мова:	Inglês
Опубліковано:	National Academy of Sciences 1987
Предмети:	Research Article
Онлайн доступ:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC305204/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3474630/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.84.14.4856
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