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Quantum mechanics/molecular mechanics investigation of the mechanism of phosphate transfer in human uridine-cytidine kinase 2

The mechanisms of enzyme-catalyzed phosphate transfer and hydrolysis reactions are of great interest due to their importance and abundance in biochemistry. The reaction may proceed in a stepwise fashion, with either a pentavalent phosphorane or a metaphosphate anion intermediate, or by a concerted S...

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Main Authors: Smith, Adam J. T., Li, Ying, Houk, K. N.
Formato: Artigo
Idioma:Inglês
Publicado: 2009
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3048851/
https://ncbi.nlm.nih.gov/pubmed/19532987
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b901429b
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