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Enantioselective Total Syntheses of (−)-Taiwaniaquinone H and (−)-Taiwaniaquinol B by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α-Arylation
We report a concise, enantioselective total synthesis of (−)-taiwaniaquinone H and the first enantioselective total synthesis of (−)-taiwaniaquinol B by a route that includes enantioselective, palladium-catalyzed α-arylation of a ketone with an aryl bromide that was generated by sterically controlle...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2011
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3042318/ https://ncbi.nlm.nih.gov/pubmed/21268578 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja110215b |
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