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Enantioselective Total Syntheses of (−)-Taiwaniaquinone H and (−)-Taiwaniaquinol B by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α-Arylation

We report a concise, enantioselective total synthesis of (−)-taiwaniaquinone H and the first enantioselective total synthesis of (−)-taiwaniaquinol B by a route that includes enantioselective, palladium-catalyzed α-arylation of a ketone with an aryl bromide that was generated by sterically controlle...

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Detalhes bibliográficos
Main Authors: Liao, Xuebin, Stanley, Levi M., Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3042318/
https://ncbi.nlm.nih.gov/pubmed/21268578
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja110215b
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