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Distinguishing Between Pathways for Transmetallation in Suzuki-Miyaura Reactions

We report a systematic study of the stoichiometric reactions of isolated arylpalladium hydroxo and halide complexes with arylboronic acids and aryltrihydroxyborates to evaluate the relative rates of the two reaction pathways commonly proposed to account for transmetallation in the Suzuki-Miyaura rea...

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Detalhes bibliográficos
Main Authors: Carrow, Brad P., Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3041853/
https://ncbi.nlm.nih.gov/pubmed/21280669
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1108326
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