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Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction
We report the isolation and reactivity of a series of “ligandless,” anionic arylpalladium complexes of the general structure [Pd(Ar)Br(2)](2)(2-) by the reaction of ((t)Bu(3)P)Pd(Ar)(Br) and bromide. These anionic complexes insert olefins at room temperature, and these fast insertions indicate that...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2818764/ https://ncbi.nlm.nih.gov/pubmed/20014842 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909306f |
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