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Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes
The oxidative addition of PhX (X = I, Br, Cl) to the complexes Pd(P(t)Bu(3))(2) (1), Pd(1-AdP(t)Bu(2))(2) (2), Pd(CyP(t)Bu(2))(2) (3), and Pd(PCy(3))(2) (4) were studied to determine the effect of steric properties on the coordination number of the species that undergoes oxidative addition and to de...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2885888/ https://ncbi.nlm.nih.gov/pubmed/19469511 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja900798s |
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