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Remarkable Levels of Enantioswitching in Catalytic Asymmetric Hydroboration
[Image: see text] TADDOL-derived phosphites and phosphoramidites are effective ligands for rhodium-catalyzed asymmetric hydroborations of β,γ-unsaturated amides, achieving up to 99% ee. However, the sense of stereoinduction, R or S, is surprisingly dependent on rather subtle features of the ligand....
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3033434/ https://ncbi.nlm.nih.gov/pubmed/20863120 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101932q |
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