Wird geladen...
Remarkable Levels of Enantioswitching in Catalytic Asymmetric Hydroboration
[Image: see text] TADDOL-derived phosphites and phosphoramidites are effective ligands for rhodium-catalyzed asymmetric hydroborations of β,γ-unsaturated amides, achieving up to 99% ee. However, the sense of stereoinduction, R or S, is surprisingly dependent on rather subtle features of the ligand....
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
|
| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3033434/ https://ncbi.nlm.nih.gov/pubmed/20863120 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101932q |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|