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Synthesis of Phantasmidine

[Image: see text] Reaction of 6-chloro-2-fluoro-3-pyridineacetamide with 1,2-bis(trimethylsilyloxy)cyclobutene in ether saturated with hydrogen chloride afforded the keto amide in 85% yield. In the key step, treatment of the keto amide with aqueous KOH in t-BuOH resulted in a tandem intramolecular a...

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Detalles Bibliográficos
Main Authors: Zhou, Quan, Snider, Barry B.
Formato: Artigo
Idioma:Inglês
Publicado: 2010
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3031734/
https://ncbi.nlm.nih.gov/pubmed/21175153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol102929m
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