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Cobalt 1,3-Diisopropyl-1H-imidazol-2-ylidene Complexes: Synthesis, Solid-State Structures, and Quantum Chemistry Calculations
[Image: see text] The reaction of (η(5)-C(5)H(5))Co(PPh(3))(2) (1) with 1,3-bis(isopropyl)imidazol-2-ylidene (Im(i)Pr(2), 17) leads to the formation of (η(5)-C(5)H(5))Co(PPh(3))(Im(i)Pr(2)) (5) in 69% yield. N-Heterocyclic carbene 17 also undergoes reaction with (η(5)-C(5)H(5))Co(CO)(2) (9) to give...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2010
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3014667/ https://ncbi.nlm.nih.gov/pubmed/21212838 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om100680c |
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