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Total Synthesis of Plukenetione A
We describe an alkylative dearomatization/acid-mediated adamantane annulation sequence which allows facile access to type A polyprenylated acylphloroglucinol (PPAP) natural products including plukenetione A. Introduction of the 2-methyl-1-propenyl moiety was achieved via stereodivergent S(N)2 and S(...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2010
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3014579/ https://ncbi.nlm.nih.gov/pubmed/20843036 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105784s |
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