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Transport properties of glass-forming liquids suggest that dynamic crossover temperature is as important as the glass transition temperature

It is becoming common practice to partition glass-forming liquids into two classes based on the dependence of the shear viscosity η on temperature T. In an Arrhenius plot, ln η vs 1/T, a strong liquid shows linear behavior whereas a fragile liquid exhibits an upward curvature [super-Arrhenius (SA) b...

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Détails bibliographiques
Auteurs principaux: Mallamace, Francesco, Branca, Caterina, Corsaro, Carmelo, Leone, Nancy, Spooren, Jeroen, Chen, Sow-Hsin, Stanley, H. Eugene
Format: Artigo
Langue:Inglês
Publié: National Academy of Sciences 2010
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3012472/
https://ncbi.nlm.nih.gov/pubmed/21148100
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1015340107
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