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A singular thermodynamically consistent temperature at the origin of the anomalous behavior of liquid water

The density maximum of water dominates the thermodynamics of the system under ambient conditions, is strongly P-dependent, and disappears at a crossover pressure P(cross) ~ 1.8 kbar. We study this variable across a wide area of the T–P phase diagram. We consider old and new data of both the isotherm...

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Autori principali: Mallamace, Francesco, Corsaro, Carmelo, Stanley, H. Eugene
Natura: Artigo
Lingua:Inglês
Pubblicazione: Nature Publishing Group 2012
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3524791/
https://ncbi.nlm.nih.gov/pubmed/23251779
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep00993
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