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An Approach Toward the Total Synthesis of 5-Hydroxyaloin A
[Image: see text] The synthesis of a thiomethyl analog of 5-hydroxyaloin A has been achieved using benzyne and naphthyne [4+2] cycloadditions with substituted furans. A regiocontrolled cycloaddition was achieved using a silicon tether, and a regioselective ring opening was accomplished using a sulfi...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3005804/ https://ncbi.nlm.nih.gov/pubmed/21082813 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol102318k |
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