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An Approach Toward the Total Synthesis of 5-Hydroxyaloin A

[Image: see text] The synthesis of a thiomethyl analog of 5-hydroxyaloin A has been achieved using benzyne and naphthyne [4+2] cycloadditions with substituted furans. A regiocontrolled cycloaddition was achieved using a silicon tether, and a regioselective ring opening was accomplished using a sulfi...

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Autori principali: Procko, Kristen J., Li, Hui, Martin, Stephen F.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3005804/
https://ncbi.nlm.nih.gov/pubmed/21082813
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol102318k
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