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A New Route to Silyl-substituted Cyclobutenones and Silylketenes
2-Silyl-cyclobutene(di)ones are obtained by an addition/substitution approach on dimethyl squarate using silyl anions. The acetal and in particular the thioacetal derivatives readily undergo electrocyclic ring opening to reactive silyl(vinyl)ketenes.
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2011
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2998044/ https://ncbi.nlm.nih.gov/pubmed/21151736 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2010.10.130 |
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