Understanding the factors affecting the activation of alkane by Cp(′)Rh(CO)(2) (Cp(′) = Cp or Cp*)

Fast time-resolved infrared spectroscopic measurements have allowed precise determination of the rates of activation of alkanes by Cp′Rh(CO) (Cp(′) = η(5)-C(5)H(5) or η(5)-C(5)Me(5)). We have monitored the kinetics of C─H activation in solution at room temperature and determined how the change in ra...

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Detalhes bibliográficos
Main Authors: George, Michael W., Hall, Michael B., Jina, Omar S., Portius, Peter, Sun, Xue-Zhong, Towrie, Michael, Wu, Hong, Yang, Xinzheng, Zarić, Snežana D.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2010
Assuntos:
Physical Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2996641/
https://ncbi.nlm.nih.gov/pubmed/21048088
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1001249107
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