A delicate balance of complexation vs. activation of alkanes interacting with [Re(Cp)(CO)(PF(3))] studied with NMR and time-resolved IR spectroscopy

The organometallic alkane complexes Re(Cp)(CO)(PF(3))(alkane) and Re(Cp)(CO)(2)(alkane) have been detected after the photolysis of Re(Cp)(CO)(2)(PF(3)) in alkane solvent. NMR and time-resolved IR experiments reveal that the species produced by the interaction of n-pentane with [Re(Cp)(CO)(PF(3))] ar...

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Detalhes bibliográficos
Main Authors: Ball, Graham E., Brookes, Christopher M., Cowan, Alexander J., Darwish, Tamim A., George, Michael W., Kawanami, Hajime K., Portius, Peter, Rourke, Jonathan P.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2007
Assuntos:
Coordination Chemistry of Saturated Molecules Special Feature
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1855363/
https://ncbi.nlm.nih.gov/pubmed/17435163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0610212104
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