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Multicatalytic, asymmetric Michael/Stetter reaction of salicylaldehydes and activated alkynes

We report the development of a multicatalytic, one-pot, asymmetric Michael/Stetter reaction between salicylaldehydes and electron-deficient alkynes. The cascade proceeds via amine-mediated Michael addition followed by an N-heterocyclic carbene-promoted intramolecular Stetter reaction. A variety of s...

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Detalles Bibliográficos
Main Authors: Filloux, Claire M., Lathrop, Stephen P., Rovis, Tomislav
Formato: Artigo
Idioma:Inglês
Publicado: National Academy of Sciences 2010
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2996425/
https://ncbi.nlm.nih.gov/pubmed/20639467
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1002830107
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