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Electronic Configuration of Five-Coordinate High-Spin Pyrazole-Ligated Iron(II) Porphyrinates

Pyrazole, a neutral nitrogen ligand and an isomer of imidazole, has been used as a fifth ligand to prepare two new species, [Fe(TPP)(Hdmpz)] and [Fe(Tp-OCH(3)PP)(Hdmpz)] (Hdmpz = 3,5-dimethylpyrazole), the first structurally characterized examples of five-coordinate iron(II) porphyrinates with a non...

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Detalhes bibliográficos
Main Authors: Hu, Chuanjiang, Noll, Bruce C., Schulz, Charles E., Scheidt, W. Robert
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2993868/
https://ncbi.nlm.nih.gov/pubmed/21047081
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic101469e
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