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General Approach to Epipolythiodiketopiperazine Alkaloids: Total Synthesis of (+)-Chaetocins A, C and (+)-12,12′-Dideoxychetracin A

A highly stereoselective and systematic strategy for the introduction of polysulfides in the synthesis of epipolythiodiketopiperazines is described. We report the first total synthesis of dimeric epitri- and epitetrathiodiketopiperazines.

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Bibliografiset tiedot
Päätekijät: Kim, Justin, Movassaghi, Mohammad
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2010
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC2987664/
https://ncbi.nlm.nih.gov/pubmed/20866039
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja106869s
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