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Synthesis of a Tricyclic Core of Rameswaralide

A tricyclic core containing a 5,7-fused bicyclic unit of rameswaralide was prepared starting from a 1,6-enyne. The synthetic sequence involved (i) ruthenium-catalyzed [5+2]-cycloaddition of 1,6-enyne, (ii) an acyl radical based approach to construct the lactone, and (iii) a regioselective installati...

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Detalhes bibliográficos
Main Authors: Trost, Barry M., Nguyen, Hien M., Koradin, Christopher
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2976576/
https://ncbi.nlm.nih.gov/pubmed/21076637
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2010.09.042
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