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Density Functional Theory Calculations on Fe-O and O-O Cleavage of Ferric Hydroperoxide Species: Role of axial ligand and spin state

Density Functional Theory (DFT) calculations are performed on thiolate bound hydroperoxide complexes. O-O and Fe-O cleavage reaction coordinates, relevant to the active sites of Cytocrome P450 and Superoxide Reductase enzymes, were investigated for both high and low spin states and for cis and trans...

תיאור מלא

שמור ב:
מידע ביבליוגרפי
Main Authors: Dey, Abhishek, Solomon, Edward I.
פורמט: Artigo
שפה:Inglês
יצא לאור: 2010
נושאים:
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC2967774/
https://ncbi.nlm.nih.gov/pubmed/21057606
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2010.03.059
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