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Oxidation of a Cyclometalated Pd(II) Dimer with “CF(3)(+)”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex
The reaction of [(bzq)Pd(OAc)](2) (bzq = benzo[h]quinoline) with “CF(3)(+)” reagents to afford the monomeric Pd(IV) aquo complex (bzq)Pd(CF(3))(OAc)(2)(OH(2)) is demonstrated. Heating this Pd(IV) adduct at 60 °C for 12 h leads to highly chemoselective Aryl–CF(3) bond-forming reductive elimination. T...
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| Asıl Yazarlar: | , , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2010
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2962414/ https://ncbi.nlm.nih.gov/pubmed/20866077 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja107780w |
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