Mechanistic and Computational Studies of Oxidatively-Induced Aryl–CF(3) Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation

This article describes the rational design of 1(st) generation systems for oxidatively-induced Aryl–CF(3) bond-forming reductive elimination from Pd(II). Treatment of (dtbpy)Pd(II)(Aryl)(CF(3)) (dtbpy = di-tert-butylbipyridine) with NFTPT (N-fluoro-1,3,5-trimethylpyridium triflate) afforded the isol...

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Bibliographic Details
Main Authors: Ball, Nicholas D., Brannon Gary, J., Ye, Yingda, Sanford, Melanie S.
Format: Artigo
Language:Inglês
Published: 2011
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3096486/
https://ncbi.nlm.nih.gov/pubmed/21513271
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201726q
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