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Mechanistic and Computational Studies of Oxidatively-Induced Aryl–CF(3) Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation
This article describes the rational design of 1(st) generation systems for oxidatively-induced Aryl–CF(3) bond-forming reductive elimination from Pd(II). Treatment of (dtbpy)Pd(II)(Aryl)(CF(3)) (dtbpy = di-tert-butylbipyridine) with NFTPT (N-fluoro-1,3,5-trimethylpyridium triflate) afforded the isol...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3096486/ https://ncbi.nlm.nih.gov/pubmed/21513271 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201726q |
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