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On the Mechanism of Palladium-Catalyzed Aromatic C–H Oxidation

The mechanism of Pd-catalyzed aromatic C–H oxidation chemistry continues to be vigorously discussed. Historically, Pd(II)/Pd(IV) catalysis cycles have been proposed. Herein, we present a detailed study of Pd(OAc)(2)-catalyzed aromatic C–H chlorination and propose dinuclear Pd(III) complexes as inter...

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Detalhes bibliográficos
Main Authors: Powers, David C., Xiao, Daphne Y., Geibel, Matthias A. L., Ritter, Tobias
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2958923/
https://ncbi.nlm.nih.gov/pubmed/20873835
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1054274
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