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Hydrogen Exchange Equilibria in Glutathione Radicals: Rate Constants

[Image: see text] The reduction of oxidized glutathione GSSG by hydrated electrons and hydrogen atoms to form GSSG(•−) is quantitative. The radical anion dissociates into GS(•) and GS(−), and the S-centered radical subsequently abstracts a hydrogen intramolecularly. We observe sequential development...

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Detalhes bibliográficos
Main Authors: Hofstetter, Dustin, Nauser, Thomas, Koppenol, Willem H.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2010
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2956374/
https://ncbi.nlm.nih.gov/pubmed/20882988
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx100185k
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