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On Catalytic Preorganization in Oxyanion Holes: Highlighting the Problems With the Gas Phase Modeling of Oxyanion Holes and Illustrating the Need for Complete Enzyme Models
Oxyanion holes play a major role in catalyzing enzymatic reactions, yet the corresponding energetics is frequently misunderstood. The main problem may be associated with the non-trivial nature of the electrostatic preorganization effect, without following the relevant formulation. That is, although...
שמור ב:
| Main Authors: | , , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2010
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2945449/ https://ncbi.nlm.nih.gov/pubmed/20825150 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo100651s |
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