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Asymmetric Total Synthesis of Vindorosine, Vindoline and Key Vinblastine Analogues

Concise asymmetric total syntheses of vindoline (1) and vindorosine (2) are detailed based on a unique intramolecular [4+2]/[3+2] cycloaddition cascade of 1,3,4-oxadiazoles inspired by the natural product structures. A chiral substituent on the tether linking the dienophile and oxadiazole was used t...

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Détails bibliographiques
Auteurs principaux: Sasaki, Yoshikazu, Kato, Daisuke, Boger, Dale L.
Format: Artigo
Langue:Inglês
Publié: 2010
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2944909/
https://ncbi.nlm.nih.gov/pubmed/20809620
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja106284s
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