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Oxidation Reactions Performed by Soluble Methane Monooxygenase Hydroxylase Intermediates H(peroxo) and Q Proceed by Distinct Mechanisms
Soluble methane monooxygenase is a bacterial enzyme that converts methane to methanol at a carboxylate-bridged diiron center with exquisite control. Because the oxidizing power required for this transformation is demanding, it is not surprising that the enzyme is also capable of hydroxylating and ep...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2935519/ https://ncbi.nlm.nih.gov/pubmed/20681546 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi1009375 |
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