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Oxidation Reactions Performed by Soluble Methane Monooxygenase Hydroxylase Intermediates H(peroxo) and Q Proceed by Distinct Mechanisms

Soluble methane monooxygenase is a bacterial enzyme that converts methane to methanol at a carboxylate-bridged diiron center with exquisite control. Because the oxidizing power required for this transformation is demanding, it is not surprising that the enzyme is also capable of hydroxylating and ep...

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Autors principals: Tinberg, Christine E., Lippard, Stephen J.
Format: Artigo
Idioma:Inglês
Publicat: 2010
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2935519/
https://ncbi.nlm.nih.gov/pubmed/20681546
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi1009375
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