Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition

Described is the construction of the N-methylwelwitindolinone C core via an efficient strategy that employs a sequential rhodium carbenoid-mediated O–H insertion, Claisen rearrangement and transannular [3+2] nitrone cycloaddition.

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Detalles Bibliográficos
Main Authors: Freeman, David B., Holubec, Alexandra A., Weiss, Matthew W., Dixon, Julie A., Kakefuda, Akio, Ohtsuka, Masami, Inoue, Munenori, Vaswani, Rishi G., Ohki, Hidenori, Doan, Brian D., Reisman, Sarah E., Stoltz, Brian M., Day, Joshua J., Tao, Ran N., Dieterich, Noah A., Wood, John L.
Formato: Artigo
Idioma:Inglês
Publicado: 2010
Assuntos:
Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2924776/
https://ncbi.nlm.nih.gov/pubmed/20733933
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2010.04.131
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