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Crystal structure of coproporphyrinogen III oxidase reveals cofactor geometry of Radical SAM enzymes

‘Radical SAM’ enzymes generate catalytic radicals by combining a 4Fe–4S cluster and S-adenosylmethionine (SAM) in close proximity. We present the first crystal structure of a Radical SAM enzyme, that of HemN, the Escherichia coli oxygen-independent coproporphyrinogen III oxidase, at 2.07 Å resolutio...

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Autors principals: Layer, Gunhild, Moser, Jürgen, Heinz, Dirk W., Jahn, Dieter, Schubert, Wolf-Dieter
Format: Artigo
Idioma:Inglês
Publicat: Oxford University Press 2003
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC291839/
https://ncbi.nlm.nih.gov/pubmed/14633981
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/emboj/cdg598
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