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Synthetic Access to Bent Polycycles by Cation-π Cyclization

[Image: see text] The presence of an ether oxygen within a chain undergoing cation–polyene cyclization has a profound influence on the stereochemistry of this important construction, apparently due to nucleophilic participation of oxygen in the cyclization process and formation of an oxonium interme...

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Autors principals: Shenvi, Ryan A., Corey, E. J.
Format: Artigo
Idioma:Inglês
Publicat: 2010
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2914341/
https://ncbi.nlm.nih.gov/pubmed/20670018
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101410g
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