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Synthesis and Regiochemistry of [60]Fullerenyl 2-Methylmalonate Bisadducts and their Facile Electron-Accepting Properties
A simple one-pot reaction using in situ chemically generated Na-naphthalenide as an electron reductant in the preferential generation of C(60)(2−) is described. Trapping of C(60)(2−) intermediate with two molar equivalents of sterically hindered 2-bromo-2-methylmalonate ester afforded two singly bon...
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| Asıl Yazarlar: | , , , , , , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2010
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2914090/ https://ncbi.nlm.nih.gov/pubmed/20524640 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo1007674 |
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