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Total Synthesis of (±)-Aplykurodinone-1: Traceless Stereochemical Guidance
[Image: see text] The total synthesis of the highly degraded steroidal natural product, aplykurodinone-1 (1), has been accomplished. Key features include a one-flask hydrolysis/retro-aldol/iodolactonization sequence to excise the C(8) hydroxymethylene functionality with retention of stereochemistry,...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2912429/ https://ncbi.nlm.nih.gov/pubmed/20513158 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1035495 |
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